Síntese de Friedel-Crafts
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PiR2 :: Química :: Química Orgânica
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Síntese de Friedel-Crafts
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![Síntese de Friedel-Crafts 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N8nLt8lS5Zs2rRJKpVC966oqKisrASrWrFixZEjR7CmH22B+7Msi0J2RFyrVKr58+dv3rxZJpONGTOGoqjy8vLg4OCIiIj169ePGzfO1dX1/fffP3nyJJQUjO/T7mZEhBPRsHQ6HUwkUs2nHpifcW784Y//BlqhUAiht2fPnq5du3p5ed27d08qlWq12sePHyPFQigUpqene3h42NradunSxdfX9+DBg6Ghod7e3m+99Vbnzp3ff//9HTt28Hg8EBS4ZRimoqIiOjraxcXFyspKIBDweDxEkuAwfE4cDmkAJpMpLCyse/fu2PH10KFDPXr0iI2NNRgMKPnNsixg8yzEZVlWq9WWlZUhpg3gVVZWXrhwwcrKysXFJTU1VSQSIQSiUqkqKip0Oh3kLRx1+EtACK0VHFCj0eTm5o4dO9bKymrVqlVwiaMJiUSC6jPN7DwxLHNycsaPH79z506YDzRNV1ZWenp6zpgxo7i4eMaMGWFhYaWlpRs2bJg7d+6NGzemTp2ak5NTWFg4duzYW7duubq6fvfddxB0T+K9S5cujY6OxufodLrq6mqMaXBwcEBAwJ07d8DEaZoWi8Vk+T5i1Ag+AUJBQUE7d+5UKpXW1tZKpbK4uHjx4sXLli0TCAS3bt1asmSJjY3N9evXEe4mKxlBtGZSgITKYZ/TNK1UKvEqkBRX2jNufwUthF5lZWW3bt369+9/8uRJhCjMQ+S5ublubm79+/dfvHjxgwcPYDFiZwqU6lUoFLt27erbt6+1tfXdu3fhLJXL5dilxmAwSCSSWbNmWVtbu7i4CAQCbGADM7j5NlUzxwY6KuT58OHDO3bsqNVqq6ur4+PjbWxstm7dirGpV8yl+S+vdyfUS3B9uVyOLXk8PDx69ux5+PBhcEPYFHC6VFdXp6amDhgwoHPnzlZWVtbW1t3rji5duri6uh48eLCwsBDuA6PRiEJQNTU1CQkJYAHHjx8HXOEsfCr9EBo4hOfBgwfxfpZlKysr/f39Z8+eTdM0PBFSqXTz5s0ODg4nTpyYPXs2pvsTdT07O9vb2/ubb74hGvvq1avXrVsnEokwygKBoKqqSq/XL1y4cOvWrdh5yMnJycbGxsnJ6dKlS3CGg7NDuautrWVZdu7cuQsWLCgqKhoyZAjLso8ePVq0aNGOHTsYhjl+/Libm1thYSHgTXKwoHo0f/6AbSFGBQ5LfB94M6ALjbLeKLeTn79JWoZhfH19raysYIpAz4HmQNP0+fPnO3ToMHv2bIReIVhIsgvcnhRFISnviy++GDx4cHh4eG1tLeiCraJA34KCgpEjR8bFxeHnU7HJp6Iamo6JiXFwcOjXr9+NGzcyMjKioqI+/PDD0aNH37t3D6H8P8ShjakA8cjj8ZYtW+bo6DhixIiioiKSnKhSqVBh/OjRo8OGDXNwcAgMDHz48CG4G+D3xGALDg4eMmTIwIEDv/322+LiYq1WC1UTWolMJgsLCxs0aND8+fOvXr2q1WrBE5tPGZZlxWJxSkoKvFwQKSzLVlVVTZ06debMmU8U13nz5sXFxRkMhnnz5vn7+9+4cWPatGmZmZl37tzx9PTMzc0dPHiwv78/2JDBYNizZ0/nzp0jIiJKSkoyMzPXr1+/atWqJzWZv/3226SkJJZl1Wr1zp07FQrFli1bVq1apdFohEKhTCa7fv36vXv38GkA+Q8//CCTybp27ZqTk3P16tVhw4atXbs2JibG1tb29OnT9+7de/DgAWx+2FlPWyILjAZBe6VSKZFIkPzDMIxKpYLbpfksoPlk/wPv/A20EonE2dl59erVer1eIpFAn5HL5Vqt9syZM2+88UZgYCB4LWSFQqFAWiyJ6IAQWq1WJpPdvHlz6tSpmzdvJvAGwhmGycrKsra2jo+Px74YKKv/B34SeRWqK/n5+f39738fNGjQRx99NGDAACsrq86dO3fo0OHAgQMQjyKR6Nl1IYh0nU4nEolWrFjh4OCQlJQklUqRRQxNRKVS3bp1y9vb29nZeevWrVqtVqlUmhtUQK/RaBQKhUePHvXw8Fi+fHlGRgZ2GEBv9Xq9XC7PyclZsmTJe++9V1ZW9sR/81S507Cos7Kyli9fjnIZUHmkUummTZu2bNlCUdTWrVsvX76s0+k2b968ePHiO3fueHh4jBkzZty4ccHBwQKBYMGCBZGRkUQfpml6y5Ytw4YN++STT6ZNm7Z27drs7GyNRpORkZGdnQ3Nv6ysLCYmxt3d/fz58/gWjUYzePDgL7/8Eq44hmH27t176tSp6upqHx8fe3v7efPmTZo06dChQ2vWrBk+fPiUKVO8vb23bt1aWVmJSUgM1ObDDCY08rrAr/H54K2Y4biHTKT2dvIraGHXjRo1atasWSaTCawR2svNmzcxGFCrsOMbhBip8YloLUgPbQe4HTVqVGxsLDgZyQEWCAQ2NjaJiYnwuyB61HyiN5+CLMsWFRV5eHhMnz796tWr8fHx0dHRhw4dwsY5Xl5eJSUl8EA8u/cYm7LTNJ2bm+vp6RkWFoZ5SRQWmUyWnJzs4eHx6aefZmVlwbjVaDRyuVwqlcIhB4KDzthua+HChRMnTvzll18QAkFKA0zBxMTEfv36FRYWwihtJlnQH7ytsrIS/m0oO+DCNTU1Op2uqqoKPkWWZUUiEcMwNTU1J06cOHLkSEFBgU6ny8vLE4vF8FlgorMsm5qaumHDhvj4eOIjoCgqJydHpVIpFIr//d//DQwMjIqKggMcbmFPT8+9e/cC1TqdrqamBsEtPp+/bdu2q1evoom7d+9evnz53LlzBw8eTE5OlsvlsEQMBgMRJM2kAChfXFwcGhq6YcOGyMjI8PDwzZs3Hz9+XCAQYGLDaGrmC1v/tl9Bq9PpaJr29PQEaAEkZNjPnj37iTeioqKCpmmFQkFohHAFFBVMBWAY4QdwgfDw8OHDhyckJGD7Y0RBSkpKbG1tExMT4WWB8/15gNZkMu3cubNnz55XrlwhyXc6ne6JiRUSEtKpU6fExETkGJBqadDTwLbqIZmk0VocJPBmjUaTn5/v4+MTEREBFYNQ5tatWx9//PH06dOLiopIc5i+RM7DBY3345zP54eHh3/xxRdVVVUAM3poMBju3LljY2MD09Ei9WCb1estBBR6iy8CYpHeiMA18KCpO5CiCG6CUDyYEclOwavQW2ie5p0BtbER0ejRowcPHhwaGpqXl1dbWws9KCMjAyKOuJTRFsQGpiWKVJIcLCh0UNAwCZVKJU7M+Vdj2cvA+cWLF995553//u//fu+991599dUOHTr079/f398f9giidOYfQsgIXw+wjVR8QIDcYH6CtoAI5HhjUIiXEaFsfBp5DwwlkgJk/kKc/wpazC03N7fAwED8A1H+I0eODBky5Pr164q6g0QIG77I4pXS0lI/P7+VK1cSIUzTdHFxcd++fa9evYovt0gai2972otisfirr77q379/eno6QjuYVTqd7tSpU/b29lu3bkV6MEgJVZaEJTADSAgUs4r8rNcZBF2MRmNxcfGnn34aERFBuJtarX4irNasWePl5QUZW+/ZJn7q9XqhUOjr67t8+XLMY4Zh0Ie8vDxbW1ssgbD4BnwsGARxK8LXAuQ3pDzoYH4zcXSRE8I1fvcEq4iQ2yQSic6dO3f48OFz587l5eVBL8U70UPy/t89wcwkjgDAlfQZVIJj1eJgAUhXr17t1avX8uXL4+PjY+uOU6dO9ejRY/z48djKkKIouVzekLBgT2Cger0eBk7D23AFM7ye5wzPEk0BbJEorST4RHzjDV9eH7Rz584l7T1xcoSEhGzevJlEX0GRhm9p7IpOpzt8+PDYsWOzs7MJR2810DIMk5mZee3aNQR7IFigiIpEory8vEePHkE1hR0O/QIkJoEQ5MQT2UvYYb1PtghaMHupVJqSkjJq1KiLFy8i+aTes038hCacmppqZWUFIxPxEpPJlJubC9AScDZ8D1w1yGND0+aTG2wF+g6gQiQAomXmCCcQxfTCDeQvZh5eSP7Ckie2okwmg8wkKxCVSqVCoSDVnkkTv3ui0WhIZh5ACHGCESSR54ZcCSQyGo1XrlyxtbU9dOgQvNAQ7x4eHm+//TZc8SBFQ5ISaiPq0dh8MJlMMpns2LFjt2/fRji9pKRk165dcNYmJCSMHj3axcXFycnp1q1byHihabq0tBSLnOBcbKz/v4IWk/Kjjz76/PPP0S2DwZCfnz9hwoSYmBhwd3iVLXKvht9GqHP37l1vb+99+/ZhsCGLWkfSEo8uBAgRI5gTRLpCwMLvj+AE1B5wRLh8QRMyYA2/1yJooWHW1tYGBgb6+/uTBXoNH7d4BSmH6MCcOXOcnZ3NvygnJ4eA1uKgwGVFsEq2wyXjSxZdwkdo/o1/+DlxxUHw4kPIek8SDPvddiFXFQpFcXExzDe8EB9LURSCSTKZzFxVNicvDITExEQrK6v9+/eT0JFarR46dGinTp1kMhm6Yf4UOVcoFFghU15eLq47GoMWj8fr06fP9u3b8bZr167Z2tpWVFQUFhY6ODjExMSUl5c/yTyxsrLKyclhGEYqlUZHR5unXjf25v8ArZOT06xZs8CMjUZjZGTkm2++GRcXh6Q/0IX0/ndPCCpC6w5i/LSapKUoChwL6XJEyGA4ZTIZTBeyLowoKgg2SqVSfCMebMxGwj0WQYvEnaKiog8++CApKUkkEsF6+V3S4Qbz1TM8Hs/KyqqyspKiKMQYs7Oze/fujfyqxuK0wAYgrdPpiMJP5CrkCYamHmCI4V3vukX11SLqaJqGnkK4JF5FDMLGmqjXovlPgPb8+fNvv/32K6+88tZbb4WGhhYWFpaUlED0kU+TSCQYlHrURleTk5M7duw4d+7cjIwMPp9/7969mTNndurU6caNGyT/tDHMoAkkk69fvz46OrpeE/hZWlrq4eHx448/VlZWVldXJyQkjBw5srKy0s3N7eDBg1hlLZFICgsLVSqVXC7Py8tbuHBhaWkpQsTEDmr48v8AraOj4/Tp0zGQRqMxPDx84sSJ9+7dMxqNCoUCjL/hKxq7glCQwWDYvXv3unXrELdAmkurSVowDpKgq9Fo1Gq1WCyGVgPdAXELpHzRNJ2VlVVUVAQ/B1Q75GlAZDU2kBZBC0mSmprq5uaGmDDZUKsxoplfJ5IWrmlbW9vFixcrlUoIRnPQWlzvhseR7qNWqx89epSSkpKenn7zP49bdUdq3ZGWlkZuuHXrVlojR3rzjps3b6anp//888+JiYnXrl1Ds+np6WlpaTdu3Lh58yaaSElJaaQdy5fT09NPnTo1duzYt956q2PHjq+88kqHDh26d+++Zs2a1NTUsrIyBCwbY7JYNXX9+vVXXnmlV69e3t7eDg4O7u7uH3zwQbdu3bBKHHqBRcwjc1Oj0YjF4mvXrjk6OgYGBvL5fFODo6SkZNCgQc7Ozhs3bly6dGm3bt3+8Y9/lJaW2tvbE+0Ali1Uhg0bNmzfvl0gEKhUKo1Gg5z5Bm/9vwv/AVoHB4eAgADi1N2xY0dwcDAi+2RmW3yLxYswNhiG2bZt2/z584uKikCLVpO0MK6wkgF2BYw0cDLoUfCFQgpRFKVQKObPnz9lypTw8PBz585lZGSgLBbCsAC/xY+1CFq4TCIiIj7++GOYlxbngcUX4qJMJsPSKJ1Ot2TJktGjR0P8GgyGrKwsSFpzn7P5q6AHYgaUlZXt3bvXy8vL3d191KhRH3/8sbu7+5gxYzw8PMaPHz+h7vCuOyZOnOjj4zNp0qTJkydPnTp1WoNjiqXDx8dnYoNjypQpPj4+48aNmzRpUkBAgJ+f35QpUxDIxYm/v//kyZP9/PwCAgIatGP5gl/d4e3tDa/v22+/3aFDh9dff/3VV18dMmTId999V1paajKZoDQ1xmFNJlNSUtKbb765evVqZO8KhcLMzMxJkya98847ycnJFEXBj2NOT5wjkY5hmLS0tHXr1vXt29fJyWnfvn0N7ywuLra3t//8889TUlIuX778+eef9+jRo7y8vE+fPnB3Y2uoU6UAABFCSURBVB/Thw8foiLCmDFjMjMz1Wo1Sf61aPXUB+2oUaMmTJgAo9xoNIaGhoaEhEgkEuIYgAuhYf8auwJhu23bts8++6y8vByBHz6f37t374SEBKgZRPlp7CUWr5uHl4grAnlXFEXBt0HACccv8YRBlYCihU/Dg9j3dcWKFe++++7f//73rl27zpgxY/369UeOHMnOziZLaiz2ByqrTqcrKiqaNm3akxx3MAixWDx9+vQJEyYgegEhafENFi9CnQbTPXz48Lhx48BSDQZDRkaGjY0NKnI0oR6TiSuVSvl8fklJSVFRUXFxcWlp6ePHj6G51dTUSKVSmUwmrzsUCoVSqSQBeTL6OMFaCPV/HnApIcRA/iLfCOt7IKCkUinW9ICHgolDJNZrpYmfWq02PT29f//+f/3rX1999VVHR8dFixZ9/fXX169fN1/42ZikRcpxcnJy7969IyMjMQ3AjnNyct57772VK1di4Rqxj8yHhgS3dDpdSUnJnj17ELw0vwfnhYWFgwcPjoqKAqCSk5Pt7Oyqq6sDAgIiIiLg/X4yBF999RWfz5dIJB999BG8UBAeTbi4fpO0er3e29vb1dWVoCg0NNTZ2Tk7Oxs5NFC3yCRo2MuGV5ATv2PHjpCQENQiEIvFfD7f2tr64sWLRHA1Qd+G7zSZTFVVVadPn16zZs2SJUuWLl0aHBy8dOnSRYsWzZ8//6u6Y/78+YsXL8Z/lzb7WLly5YoVK8aPH//uu++++uqrHTt2/Nvf/vb666+/++67/v7+ycnJMNIsdgkQpWmax+P5+vpGREQgBKdQKNzc3KZPn458AyjMFt9g8SLmLjS6qKgoNzc3zACTyXTr1q1evXoJhcKnld4WG3pRLsLRmp6ePm7cuGXLln3//fepqalisbgxoWTxuwwGQ0pKip2d3datW0lUBulAPXr0CA0NRQ0NiwFOrARCc1Kp9P79+1hO07AhHo/n4OBw/vx5pI7Ex8fb29sXFxefPXvW3t5+48aNW7ZsmT59enBwcFlZ2RPp+vXXX6O4mlarlUqlFltHK02B9ujRo9bW1ufOnYNqB6dZw841dgXeV4ZhwsPDIyIikFiD5NtnBK1cLs/KyoqLi4uJiTl9+vSZM2fi4uLOnDkTGxt7qu6IjY09e/bs6dOnY5p9xMbGxsTEHDhwYOzYsX/729/+8pe/vPbaax07duzateucOXNOnz5dVlaGGJrF77UIWrjBvvjiCz8/P8hYSHuLb2jsIvHnHTlyxNXV9SUH7ZN06OrqarFYnJ2dDd8E/IjNlyXAQ3JyMmr9QPgLBIKIiAhXV1cbGxs+n481xha5IakojICLXC5vTCTK5fL4+Pjy8nJE6aqrq6Ojo6VSaVVV1dmzZ/fv379p06bdu3eXlJRAJUxNTa2oqEDGBNENLc6KpkDL4/EmTpwYFRUF3a+4uBh+VIsvangRoH306FFAQMD+/fuhEWk0mmeXtNBwIJ9hssJjhBgGWfmFG4ji0MQJdB7Efp4sK+nUqdN//dd/zZkzJy0tLSsr60nNOqy5hdxr+KVIJIItYC5pwcX37dvn7u4Oq/ipBILJZMICXbDqmTNnenh4EFfWSytp4VaFTxGqnEU/nMVhgvrDsmxCQsLrr7/erVs3Nzc3e3v7oUOH9unTZ+TIkdHR0SgABC7c8CXmrm/Mw4b34Aq80NDOwKylUinJ1pZIJI8fP6YoCk4HKLNisRghKAQgG7N6mgLtk0kcEhKycOFCLI+kabqqqqr5LA3xhujoaHt7+6SkJGBGrVY/I2gJ9ohpCiyR6y04UavVlZWVSBW4fPlyZmYmj8eTy+V4FfgCqaRjcZAsSlpkaGZmZo4YMaKmpoYwEYtvsHgRPgmwg86dO//0008vuaSF3qFSqYRCIRbiIsLZfG6IMdVoNDwer7i4uKqqqqKiorS0tLy8PD8/H7m6tbW1UIMbDgoeJ2FR9IckoprfTyKFxJmCHcB1Oh3KJACoEGaYG+Ds5hPY/IXkvCnQsix75cqVYcOGnThxAovsGtMEyOvMT4xGY1VV1erVq1esWIHscJSZf0bQqlQq+MOINQJswI0EPw0pHNGEP6Pev+BMxipt8HJ4I0BxpFKr6g7zbyTnFkGLGlFVVVXe3t47d+7ESywOMHmP+Ql6iHxvHo9nZ2dHvCYvs01LamuBPuBizZcliKaQmB/SxbAsHIOIESfBWPMRIYFlk8kEzyJEosVVViTcqNFoamtroawhxoNyOXAUYyENrpsL+Sa+qCnQqtXqJwmA69atmzhxYkVFBaIj9b6hiZ8qleqHH36YMGHClStX4D+A+vqMoCV8C8VcMKdJbBn9gc8MeYv1wGnxJ9LfYIKSJDiwQJCeuJobI6VF0GJxplKpDA0NHT9+PJJdLFpKFsmo0WhQUEKpVHp5eQUGBoKnQBt8adVjJJZh2QASdJEIZZGGFi9iHpLgBRLgkCKOMD5JaG34OAmwAa6YHhbHlGQmY8pBM0flJujVMI/h9IIVTRZsEB91ww78FvKBMjBp0iT4J/FVeIDH43l6eh46dIjkzZozIaKWgIjEIazVak+ePDlw4EDUiEDuOKzN4uLinj17nj17FqAC02oMDA07DUWi3nVoFOYXScYfOHHTf7HaBsQl6UESiQT8mOg5TdgwJOu1oKDA19c3MjISX4eVEr/88ouXl1dkZCQmHOkn4Qi4AjUYHg44D8F6k5OTu3XrRrwU8GnduXPHzs5OKBQ+LTMlrb+IJyigjyAfAQOZdc38Iqg8ZBEL5gZN01KplARKyMvrvRM34yLkR70bzH9CGSSPmI8UxAxCymiLTDa4LZooePirpMU+PTNnzvT09ER9XZICLpFIEhMTR44cGR4eDscalg0Q3w+USch6ROFMJtOxY8fs7OwiIiKwNBFMAcu+S0tLu3TpAv8WpBkcXeZf+8KdA12I086YMWP//v2AFsmGPX78uJ+fX1paGtGswAIgovG9er2+oqICOeXIgKVp+ty5c0OGDFm5ciV4BxY86PX6hw8fDhw4kFT2euEoxnW4xRT4TT1WKpUBAQG2trbE+QEHHRAfGxs7a9YsPz+/c+fOmUwmVKAGh4OCTvYiyM/P37ZtW79+/aKiosgExS4v8JU9ePCgV69e8Ccjbvm0KQct/trn9yBAK5PJSktLZ82atWvXLvAyqAAMw5SWlq5cudLHxycvL4+iKLiFQUDYM/T/L/6OqCxocv78+WHDhj2JOaPQIVJKUGLm7t27AwYMQNGW5/dd3JvbIQV+BS3wmZSU1LVr19mzZ0dEREAGQpHAUuaHDx8CjYGBgadPn0axKJLzaDAYHj9+HBYWNnr06CFDhuzevRs6NuQGbNonxbvWrVvn6+uLFUnAOTxARM1uhzRqTpfgDFMoFI8ePfLz8/v++++RMoRoDWr38Pn8L7744uOPP0bhQuzQA90J5YKRdwnPBEVRZ86c6du3b0hISHl5OTQrmPE0TQuFwl9++cXe3p7P55MyEc3pJ3fPn4ACv4EWMyYvL+/s2bP/8z//ExAQcPPmTeKPhlWNePGCBQuGDRv24YcfDhs2bOjQoW5ubsOGDXNycho6dOjIkSOPHj2KCiMw2MiKvGvXrvn5+b3xxhsZGRm3b9+GgxeZ0xbN1BeLuAAnkvXWrl3bs2fPCxcuVFVVQYoiXIQaqwcOHEDNt+vXryNcgQRJLNNHhlN+fv6nn37ap0+fb775BiUOZXUHjF5k/y9YsKB37958Ph+G04tFLq63z0KBX0GLPAyDwYBwZXp6+ldfffXuu++GhYVJpVJSDRB1bpVKZUVFRVZW1pkzZ4KCglxcXD799NMzZ86UlZWVl5cjHlNaWgqcMwxTWFi4YMGCzp07T58+vbCwUCaToe45jH7EgZrviHqWr31+z2JVEPRegUAQFBRkb2/v6+tbVFREtq5ETqlGoykoKFi1alWPHj1sbGz8/f2PHj3K4/FUKlVOTs7MmTO7du3avXv36dOn379/H3ECZFPDyyCXy3/88cfOnTvPmzfv/v37yGt/0an3/MblT/nm30Arl8urq6sxS6RSqUQiSUpKGjVqVKdOneLi4mpqarD6FHWM4T6BEw+r9pD8TfS3mpoajUZTWlq6bdu27t27Ozo6pqSkIOUInm7sM4LSROZetReUyrBOsdYPUTuKoiZPnjxy5MgNGzbweDxYqnApg4YMw/z73//28PCws7MbOHCgjY2NtbV17969Dxw4gLcplUqsnoULqqam5vDhw2+++aa3t/edO3ewiAeOx+bHfl9Q8nLdNqfAr6BF8hRix6jfgzQgiqI2btxob28/fvz49PR0yBOU5EKMB8W+YPoSB7dEIhGJRJcuXXJ0dOzfv//u3buxIhQLR0QiEaIacG1jgpr36QU9JwEb9B8W+6ZNm8aMGePo6Hjx4sX79++TWg0kYxaoQ0VPRB2x/SQeJ6pNamrqtGnTbG1tsV8O1BOs8HpBycV1u8UU+BW0Fp9HgRLUy/zqq6/c3Ny2b9+enJwMQxexHKPRiAQ9hCJg2iUlJa1ater9999fvnw5iqqRVJIX3eFkkVCNXWQYRqFQiESiL7/80snJydPTE4Yu9BTIWzAySFSwNrjuEFdTqVTJyclhYWG2trYLFy5MSkpqrC3u+stDgaZAi+1nEfOVy+WxsbG+vr729vbh4eG5ublisdi8+hnCOTdv3vzhhx8GDRo0b968vXv3wnaFPkwUyJeHuCaTCSngtbW1aWlp8+bNc3d3X7JkCbbkhtcKBfJRCArZXSTj58GDB2FhYY6OjrNmzQoLC0O6yEtFPe5jLVKgKdBilQm2jcLcKioqCg8P9/f3nzBhQlxcHNRgKHJyufz48eMuLi6TJ0/G1piovoeILtmW5qVymRDPORiWRCK5cOHCnDlzvL29Fy1aBKMUu0UjtwY7NsDOP3/+/IQJE6ZOnRoZGYmq4qiDwZmvFufxS3WxKdBizQGSK6D9IqUpKysrJCTE1dXVy8vr8ePHRqPxwYMHnp6ebm5umzZtun//PhLlcTOKSPxpDNenmhyAIup9QmExmUw8Hu/SpUv29vaffPIJArak5B1itiUlJePHj3dxcVm5cmV6ejr8fzqdTiKRyGSyp1qG9lS95W5+USjQFGjhLEHVZvhIiIu4qqoqNzd34MCBgwYNQnj2k08+yczMrK2tVSgU2J8O6hwRrSQN40UhzR/ST4lEAtUXe5RhiZJOp7t3797u3bv79u07e/bsnJwcGBpPcrPXr1///vvvDx8+PDU1FXUMAGlUJ4Hb7w/pGPeSF5cCTYEWa2XM9zjCPj1I0DMYDCUlJQKBICQk5N69ezKZTCqVorwQFsqQ5Ar4XeAUJRh+cUnW/J5DMGI7NoRtEPLB7pI0TWdkZPj4+PTo0WP79u1XrlwZMWJEv379Ll++jJ278AicBaDhy6mwNJ/gL8mdTYHWfPkovCZYmkA0PcwhoVCINS6YncjCxapFstQGyfGQJy8JZfGZ0JCx0grJjAqFAheRJlVTU/Pjjz8OrTs++eQTCGSE00A0ZC+Dqi8V6biPbYwCTYG2sWe46xwFOAq0IQU40LYh8bmmOQq0hAIcaFtCNe4ZjgJtSAEOtG1IfK5pjgItoQAH2pZQjXuGo0AbUoADbRsSn2uao0BLKMCBtiVU457hKNCGFOBA24bE55rmKNASCnCgbQnVuGc4CrQhBTjQtiHxuaY5CrSEAhxoW0I17hmOAm1IAQ60bUh8rmmOAi2hAAfallCNe4ajQBtSgANtGxKfa5qjQEsowIG2JVTjnuEo0IYU4EDbhsTnmuYo0BIKcKBtCdW4ZzgKtCEFONC2IfG5pjkKtIQCHGhbQjXuGY4CbUgBDrRtSHyuaY4CLaEAB9qWUI17hqNAG1KAA20bEp9rmqNASyjw/wA8hu52tJHUNQAAAABJRU5ErkJggg==)
O reagente A e o produto B são, respectivamente:
![Síntese de Friedel-Crafts OAAAAAElFTkSuQmCC](data:image/png;base64,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)
O reagente A e o produto B são, respectivamente:
- Gabarito:
- d
guuigo- Recebeu o sabre de luz
- Mensagens : 115
Data de inscrição : 20/08/2023
Re: Síntese de Friedel-Crafts
Olá!guuigo escreveu:Considere a seguinte rota sintética:
O reagente A e o produto B são, respectivamente:Por que não poderia ser letra E?
- Gabarito:
d
A questão trata sobre a síntese de Friedel-Crafts, mais especificamente uma Alquilação de Friedel-Crafts.
O benzeno (C6H6), para formar o tolueno (metilbenzeno) e o ácido clorídrico (HCl) como subproduto, teremos um mecanismo reacional via substituição eletrofílica. Como teremos, ao final da reação, um grupamento -metil ligado diretamente ao benzeno, isso implica dizer que o hidrogênio que anteriormente ocupava tal posição foi substituído, formando uma ligação com o cloro. Ou seja, juntando essas duas informações, chegamos a conclusão que o segundo reagente se trata do clorometano (CH3Cl). Para essa reação acontecer, intermediada por cloreto de alumínio (AlCl3) como catalisador, haverá junção do eletrófilo (H) com o nucleófilo (Cl), formando HCl. Dessa forma, o carbono que perdeu essa ligação no benzeno está com uma carga negativa (δ-), assim, ele se junta com o radical -metil do clorometano, que se apresenta com uma carga positiva (δ+).
Creio que seu erro em considerar a opção (E) foi associar o cloreto de alumínio ao segundo reagente, o que não é o caso. Ele apenas atua como catalisador, sendo necessário para que a reação aconteça. Lembre-se sempre que a maioria das reações orgânicas não são tão espontâneas quanto as reações inorgânicas, por isso é comum nos depararmos com catalisadores com certa frequência. Outros catalisadores comuns de aparecerem:
- Permanganato de Potássio (KMnO4).
- Ácido Sulfúrico (H2SO4).
- Dicromato de Potássio (K2Cr2O7).
- ∆θo X (Temperatura reacional específica).
matheus_feb- Jedi
- Mensagens : 318
Data de inscrição : 18/06/2024
guuigo gosta desta mensagem
Re: Síntese de Friedel-Crafts
O benzeno seria capaz de reagir com o metano (CH4) por substituição eletrofílica???matheus_feb escreveu:Olá!guuigo escreveu:Considere a seguinte rota sintética:
O reagente A e o produto B são, respectivamente:Por que não poderia ser letra E?
- Gabarito:
d
A questão trata sobre a síntese de Friedel-Crafts, mais especificamente uma Alquilação de Friedel-Crafts.
O benzeno (C6H6), para formar o tolueno (metilbenzeno) e o ácido clorídrico (HCl) como subproduto, teremos um mecanismo reacional via substituição eletrofílica. Como teremos, ao final da reação, um grupamento -metil ligado diretamente ao benzeno, isso implica dizer que o hidrogênio que anteriormente ocupava tal posição foi substituído, formando uma ligação com o cloro. Ou seja, juntando essas duas informações, chegamos a conclusão que o segundo reagente se trata do clorometano (CH3Cl). Para essa reação acontecer, intermediada por cloreto de alumínio (AlCl3) como catalisador, haverá junção do eletrófilo (H) com o nucleófilo (Cl), formando HCl. Dessa forma, o carbono que perdeu essa ligação no benzeno está com uma carga negativa (δ-), assim, ele se junta com o radical -metil do clorometano, que se apresenta com uma carga positiva (δ+).
Creio que seu erro em considerar a opção (E) foi associar o cloreto de alumínio ao segundo reagente, o que não é o caso. Ele apenas atua como catalisador, sendo necessário para que a reação aconteça. Lembre-se sempre que a maioria das reações orgânicas não são tão espontâneas quanto as reações inorgânicas, por isso é comum nos depararmos com catalisadores com certa frequência. Outros catalisadores comuns de aparecerem:
- Permanganato de Potássio (KMnO4).
- Ácido Sulfúrico (H2SO4).
- Dicromato de Potássio (K2Cr2O7).
- ∆θo X (Temperatura reacional específica).
guuigo- Recebeu o sabre de luz
- Mensagens : 115
Data de inscrição : 20/08/2023
Re: Síntese de Friedel-Crafts
Boa noite!guuigo escreveu:O benzeno seria capaz de reagir com o metano (CH4) por substituição eletrofílica???matheus_feb escreveu:Olá!guuigo escreveu:Considere a seguinte rota sintética:
O reagente A e o produto B são, respectivamente:Por que não poderia ser letra E?
- Gabarito:
d
A questão trata sobre a síntese de Friedel-Crafts, mais especificamente uma Alquilação de Friedel-Crafts.
O benzeno (C6H6), para formar o tolueno (metilbenzeno) e o ácido clorídrico (HCl) como subproduto, teremos um mecanismo reacional via substituição eletrofílica. Como teremos, ao final da reação, um grupamento -metil ligado diretamente ao benzeno, isso implica dizer que o hidrogênio que anteriormente ocupava tal posição foi substituído, formando uma ligação com o cloro. Ou seja, juntando essas duas informações, chegamos a conclusão que o segundo reagente se trata do clorometano (CH3Cl). Para essa reação acontecer, intermediada por cloreto de alumínio (AlCl3) como catalisador, haverá junção do eletrófilo (H) com o nucleófilo (Cl), formando HCl. Dessa forma, o carbono que perdeu essa ligação no benzeno está com uma carga negativa (δ-), assim, ele se junta com o radical -metil do clorometano, que se apresenta com uma carga positiva (δ+).
Creio que seu erro em considerar a opção (E) foi associar o cloreto de alumínio ao segundo reagente, o que não é o caso. Ele apenas atua como catalisador, sendo necessário para que a reação aconteça. Lembre-se sempre que a maioria das reações orgânicas não são tão espontâneas quanto as reações inorgânicas, por isso é comum nos depararmos com catalisadores com certa frequência. Outros catalisadores comuns de aparecerem:
- Permanganato de Potássio (KMnO4).
- Ácido Sulfúrico (H2SO4).
- Dicromato de Potássio (K2Cr2O7).
- ∆θo X (Temperatura reacional específica).
Não. A reação entre o benzeno e o metano não é possível mesmo com a utilização de catalisadores/pH específico/temperatura de ativação.
O mecanismo de substituição eletrofílica, para acontecer, o segundo reagente obrigatoriamente deve possuir uma extremidade nucleofílica (Cl, Br, I...) para reagir com um dos hidrogênios do benzeno.
Considerando esta possibilidade, teríamos a formação de um hidrácido e tolueno (metilbenzeno), exatamente como você verificou nesta questão.
Repare bem: Embora esta reação que citei precise de uma extremidade nucleofílica, ela ainda é do tipo eletrofílica, uma vez que é o hidrogênio oriundo do benzeno que sofre o mecanismo de substituição. Mas como ele assume carga positiva (pois o carbono possui maior eletronegatividade), a reação apenas pode ocorrer caso este mesmo hidrogênio reaja com um núcleo negativo, tal como um dos elementos que já citei anteriormente (90% das vezes será o cloro).
Espero que tenha entendido.
matheus_feb- Jedi
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