Constantes de Equílibrio(ka,kb)
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PiR2 :: Química :: Físico-Química
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Constantes de Equílibrio(ka,kb)
Em outubro de 2017 a Vigilância Sanitária de Florianópolis emitiu um alerta epidemiológico aos profissionais de saúde, em relação a presença da toxina paralisante- PSP (sigla em inglês para Palaytic Shellfish Poisoning) em moluscos bivalves (ostras, vieiras, mexilhões e berbigões), ficando proibida a retirada, comercialização e consumo dos produtos procedentes em várias áreas do estado de Santa Catarina. O PSP é causado por toxinas do grupo saxitoxina (STX) que causam sintomas como diarreias, náuseas, vômitos, dores abdominais, perda de sensibilidade nas extremidades do corpo e, casos severos, paralisia generalizada e óbito por falência respiratória. (Secretaria Municipal de Saúde de Florianópolis – Diretoria de Vigilância em Saúde – Gerência de Vigilância Epidemiológica, 2017). Estrutura química da saxitoxina (STX)
![Constantes de Equílibrio(ka,kb) 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)
Quais os valores de Kb aproximados para a guanidina das posições A e B a 25°C respectivamente?
a) 1,90x10-3 ; 1,66 x10-6
b) 1,90x10-1 ; 1,66 x10-1
c) 1,90x10-3 ; 1,66 x10-1
d) 1,91 x10-1 ; 1,66 x10-6
e) 1,90x10-2 ;1,66 x10-5
Gab;A
Quais os valores de Kb aproximados para a guanidina das posições A e B a 25°C respectivamente?
a) 1,90x10-3 ; 1,66 x10-6
b) 1,90x10-1 ; 1,66 x10-1
c) 1,90x10-3 ; 1,66 x10-1
d) 1,91 x10-1 ; 1,66 x10-6
e) 1,90x10-2 ;1,66 x10-5
Gab;A
Última edição por David Harmor em Qui 15 Ago 2024, 17:21, editado 1 vez(es)
David Harmor- Iniciante
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Re: Constantes de Equílibrio(ka,kb)
Onde está o comando da questão?David Harmor escreveu:Em outubro de 2017 a Vigilância Sanitária de Florianópolis emitiu um alerta epidemiológico aos profissionais de saúde, em relação a presença da toxina paralisante- PSP (sigla em inglês para Palaytic Shellfish Poisoning) em moluscos bivalves (ostras, vieiras, mexilhões e berbigões), ficando proibida a retirada, comercialização e consumo dos produtos procedentes em várias áreas do estado de Santa Catarina. O PSP é causado por toxinas do grupo saxitoxina (STX) que causam sintomas como diarreias, náuseas, vômitos, dores abdominais, perda de sensibilidade nas extremidades do corpo e, casos severos, paralisia generalizada e óbito por falência respiratória. (Secretaria Municipal de Saúde de Florianópolis – Diretoria de Vigilância em Saúde – Gerência de Vigilância Epidemiológica, 2017). Estrutura química da saxitoxina (STX)
a) 1,90x10-3 ; 1,66 x10-6
b) 1,90x10-1 ; 1,66 x10-1
c) 1,90x10-3 ; 1,66 x10-1
d) 1,91 x10-1 ; 1,66 x10-6
e) 1,90x10-2 ;1,66 x10-5
Gab;A
matheus_feb- Jedi
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Re: Constantes de Equílibrio(ka,kb)
David rs... acho que você se esqueceu de escrever a pergunta.
Lipo_f- Jedi
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Re: Constantes de Equílibrio(ka,kb)
Editado,foi mal rsrsrsr
David Harmor- Iniciante
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Re: Constantes de Equílibrio(ka,kb)
Vale para pares de ácidos-bases conjugados: KaKb = Kw. A 25°C, 10^-14. Daí,
Kb1 = 10^-14/5.24 . 10^-12 ≅ 1.90 . 10^-3
Kb2 = 10^-14/6.02 . 10^-9 ≅ 1.66 . 10^-6
Kb1 = 10^-14/5.24 . 10^-12 ≅ 1.90 . 10^-3
Kb2 = 10^-14/6.02 . 10^-9 ≅ 1.66 . 10^-6
Lipo_f- Jedi
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David Harmor gosta desta mensagem
Re: Constantes de Equílibrio(ka,kb)
Opa, amigo estava resolvendo a questão alguns depois para fixa-la e fiquei com uma duvida rs.
Como vc interpretou que essa era a equação a ser usada?
Não há indícios da base conjugada ou uma equação descrita para entender qual é a base conjugada, muito menos qual deles é o ácido.
Peço desculpas pelo incômodo
Como vc interpretou que essa era a equação a ser usada?
Não há indícios da base conjugada ou uma equação descrita para entender qual é a base conjugada, muito menos qual deles é o ácido.
Peço desculpas pelo incômodo
David Harmor- Iniciante
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Re: Constantes de Equílibrio(ka,kb)
Olá, David!David Harmor escreveu:Opa, amigo estava resolvendo a questão alguns depois para fixa-la e fiquei com uma duvida rs.
Como vc interpretou que essa era a equação a ser usada?
Não há indícios da base conjugada ou uma equação descrita para entender qual é a base conjugada, muito menos qual deles é o ácido.
Peço desculpas pelo incômodo
A interpretação está na própria pergunta. Ele quer a constante de basicidade (Kb) da guanidina, para as posições A e B. Entretanto, ele nos forneceu apenas valores de pKa. Sabemos, pelo estudo de equilíbrio de ácidos e bases conjugados, que valores de Ka podem chegar ao seu valor de Kb. Assim, se conseguirmos obter o valor de Ka para as duas posições A e B da guanidina, podemos chegar em seu valor de Kb, correto?
Você já deve saber que, matematicamente: [Ka] = -(log[pKa]) Encontre o valor do Ka.
Encontrado o Ka de ácido conjugado da guanidina, podemos encontrar, de forma intuitiva, seu respectivo valor para Kb. Lembra que, nos estudos de ácidos e bases inorgânicos, pH + pOH = 14? Ou seja, um conjunto ácido-base geram, ao final, um par neutro. Sabemos que a água, em condições normais, é completamente neutra. Esse raciocínio justifica a constante Kw, a constante de ionização da água, respectivamente igual a Kw = 10-14. Ou seja, se Kw advém de um conjunto ácido-base, podemos então afirmar que elas estabelecem a seguinte relação:
[Ka] . [Kb] = Kw
Calcule Ka. Aí basta repetir o mesmo processo para a outra posição.
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